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Can any one please help me on this ?
Error: Unknown property 'core.email.template.EmailTemplateComponentController.Account'
<messaging:emailTemplate subject="New email and New Case" recipientType="User" relatedToType="Case">
<messaging:plainTextEmailBody >
*** CASE EMAIL ALERT For NEW CASE***
The following case has a new inbound email associated with it and it has been reopened:
Case: {!relatedTo.CaseNumber}: {!relatedTo.Subject}
Web name: {!relatedTo.SuppliedName}
Web company: {!relatedTo.SuppliedCompany}
Web e-mail: {!relatedTo.SuppliedEmail}
Web phone number: {!relatedTo.SuppliedPhone}
Company: {!Account.Name}
Contact Name: {!Contact.Name}
Contact e-mail: {!Contact.Email}
Contact phone number: {!Contact.Phone}
Case #: {!Case.CaseNumber}
Subject: {!Case.Subject}
Description:
{!Case.Description}
Click on the link to access the case: {!Case.Link}</messaging:plainTextEmailBody>
</messaging:emailTemplate>
<messaging:emailTemplate subject="New email and New Case" recipientType="User" relatedToType="Case">
<messaging:plainTextEmailBody >
*** CASE EMAIL ALERT For NEW CASE***
The following case has a new inbound email associated with it and it has been reopened:
Case: {!relatedTo.CaseNumber}: {!relatedTo.Subject}
Web name: {!relatedTo.SuppliedName}
Web company: {!relatedTo.SuppliedCompany}
Web e-mail: {!relatedTo.SuppliedEmail}
Web phone number: {!relatedTo.SuppliedPhone}
Company: {!Account.Name}
Contact Name: {!Contact.Name}
Contact e-mail: {!Contact.Email}
Contact phone number: {!Contact.Phone}
Case #: {!Case.CaseNumber}
Subject: {!Case.Subject}
Description:
{!Case.Description}
Click on the link to access the case: {!Case.Link}</messaging:plainTextEmailBody>
</messaging:emailTemplate>

You need to do it like this