REST API Developer Guide
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Process Rules
Accesses a list of all active workflow rules. Use the GET
method to retrieve records or fields. Use the HEAD method to retrieve information in
HTTP headers. Use the POST method to trigger all active workflow rules.
To access all workflow rules that are associated with a specific sObject, use the Process Rule List for an sObject resource. To access a specific workflow rule that is associated with a specific sObject, use the Process Rule for an sObject resource.
Cross-object workflow rules can’t be invoked using REST API.